Corrosion is the result of electrochemical
activity ... galvanic action. Scientific studies have proven that metals having a higher
electrical potential will corrode and degrade in a typical corrosion cell, while
protecting other metals having a lower electrical potential. Of all metals, Zinc has the
highest electrical potential, as shown in the Practical Galvanic Series table below. The
voltages are typical in neutral soil conditions and water measured against a copper
sulfate reference electrode.
| Metal |
Volts |
| Zinc (Mil Spec anodes) |
-1.1 |
| Aluminum (commercially
pure) |
-0.8 |
| Mild steel (clean) |
-0.5 to -0.8 |
| Mild steel (rusted) |
-0.2 to -0.5 |
| Cast iron (not
grashitized) |
-0.5 |
| Lead |
-0.5 |
| Mild Steel (in concrete) |
-0.2 |
| Copper, brass, bronze |
-0.2 |
| High silicon cast iron |
-0.2 |
The most common type of
corrosion cell is a simple Battery. The outer case is made of a zinc alloy having a
negative charge, the anode. The center post is a carbon rod having a positive charge, the
cathode. Separating the two is a filler, the electrolyte. In operation, the positive
current charge rushes from the zinc anode to the cathode, causing eventual pitting of the
zinc case. As the electrochemical activity stabilizes, the battery loses strength. The
aggressive nature of the electrolyte determines the current output and the life of the
battery.
The same phenomenon occurs in submerged water and gas
mains. The pipes and fittings are buried in an electrolyte, the moist soil. The
unprotected lines and fittings, the cathode, have a positive charge and the current
generated is discharged directly into the soil in the electrochemical process of
corrosion.
Corrosion failures of water and gas mains are directly
related to the failure of either the bolt/nut combination, or the flanges secured by the
combination.

By adding a sacrificial metal, zinc caps, the natural
current flow is altered, flowing from the anode (the zinc caps) to the cathode (the pipe
and fittings), through the electrolyte (the moist soil) and preventing corrosion.